taiyangnews 06月03日 20:38
Low-Temperature HJT Manufacturing Adapts To Wider Wafer Variants
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异质结(HJT)电池作为一种高效电池技术,逐渐成为太阳能领域的重要竞争者。它结合了晶体硅和薄膜非晶硅,在光伏电池技术中独树一帜。尽管HJT具有低温处理、工艺步骤少、高双面性和优异的温度系数等优势,但由于其较高的成本,使其难以成为主流。然而,HJT技术已吸引了一批忠实的支持者,建立了大规模生产设施。本文总结了HJT领域的一些重要进展,特别是在晶圆质量、厚度以及未来发展方面的关键突破。

💡**晶圆质量与兼容性:** HJT技术对晶圆质量的要求相对较低,可以通过热处理工艺(退火)去除金属杂质,可以使用来自不同位置的硅锭和坩埚生产的晶圆。此外,HJT还兼容低成本的CZ技术,该技术允许连续生产,即使氧含量较高,也不会影响HJT的性能,因为HJT不涉及高温步骤。

🔬**晶圆电阻率与寿命:** HJT电池的晶圆主要有两种电阻率范围:0.3 - 2.1 Ω·cm和1–7 Ω·cm,其中0.3 - 2.1 Ω·cm是主流。HJT晶圆的少数载流子寿命取决于电阻率,通常HJT晶圆的寿命要求低于TOPCon晶圆。

🔪**晶圆切割与薄化:** 大多数HJT生产商采用半片晶圆技术,以提高硅锭利用率。HJT技术在晶圆厚度方面取得了显著进展。领先的HJT制造商华晟能源已开始使用120 µm的晶圆,并计划在2024年底达到110 µm。在2024年12月的会议上,华晟和东方日升宣布100 µm晶圆已投入生产,90 µm晶圆正在评估中。然而,晶圆厚度进一步降低到80 µm以下,可能会影响效率。

📈**行业预测:** CPIA和ITRPV都预测晶圆厚度将持续下降,但预测的具体数据和时间表有所不同。CPIA预计HJT技术将引领晶圆厚度降低,到2026年达到100 µm,到2030年达到90 µm。而ITRPV预测的晶圆厚度相对较高,预计到2032年将达到100 µm。

Heterojunction (HJT) is a prominent high-efficiency cell technology that has evolved into a serious contender for mainstream solar production. Built on the foundation of marrying crystalline silicon with thin-film amorphous silicon layers, it stands out as a unique approach among PV cell technologies that has been particularly attractive to newcomers looking to avoid launching yet another ‘me-too’ product. However, despite its promise, HJT has often remained a contender rather than becoming mainstream, largely due to its higher costs both in terms of CapEx and OpEx. Nevertheless, the technology has secured a loyal group of serious followers who have established multi-gigawatt-scale manufacturing facilities, driven by several undeniable advantages. HJT offers benefits such as low-temperature processing, a reduced number of process steps, high bifaciality, and a superior temperature coefficient. Moreover, it is widely regarded as an ideal platform for the development of future tandem solar cells. Against this backdrop, we summarize a range of important developments in the HJT segment in this chapter.

Like with other commercial advanced cell technologies, HJT also uses n-type base wafers. However, compared to its peer technologies, HJT is most forgiving in terms of wafer quality.

Electrical Parameters

It is already established that in order to address the requirement for high wafer quality, the industry has adopted a heat treatment process (annealing) that mimics gettering, a process of removing metallic impurities with thermal treatment. As a result, HJT can now use wafers from different positions of the ingot and production runs of the crucible. Annealing is now the standard in the HJT process sequence. An important development with respect to wafer requirements for HJT is its compatibility with low-cost wafers originating from the rechargeable Czochralski (CZ) technology. In this method, after the initial silicon melt is depleted during ingot pulling, the crucible is refilled with a new charge of polysilicon, allowing continuous operation.

While the process results in higher oxygen content, this is not a concern for HJT. That’s because HJT does not involve steps involving high temperatures, which would otherwise activate oxygen-related defects. Moreover, it also allows the integration of another low-cost process upstream. The ingot pulling process can also use the low-cost granular silicon produced with the fluidized bed reactor (FBR), which results in slightly lower purity than the standard method, but still aligns well with the requirements for HJT. Wafer producers like LONGi (with its new TaiRay wafer technology) have also raised the bar in overall wafer quality.

The table below lists the typical wafer specs for HJT cells. HJT wafers come in 2 main resistivity ranges: 0.3 - 2.1 Ω·cm and 1–7 Ω·cm, with 0.3 - 2.1 Ω·cm being the mainstream. The minority carrier lifetime of HJT wafers varies significantly depending on resistivity. In general, HJT wafers have lower lifetime requirements compared to TOPCon wafers.

When it comes to physical properties, the majority of HJT producers have adapted to half-wafer processing. This enables them to improve the ingot utilization rate by deriving the half bricks from the slide slabs of the ingot.

An even more compelling topic related to wafers when it comes to HJT is thickness; to be specific, the ability to process thin wafers. Huasun Energy, a leading HJT manufacturer, reported using wafers around 120 µm thick in mid-2024, with a target to reach 110 µm by the end of that year. At the TaiyangNews High Efficiency Solar Technologies Conference held in December 2024, Huasun, as well as Risen, another HJT leader, announced that 100 µm has already entered production, while a thickness of 90 µm is being evaluated. However, companies put an 80 µm cap for wafer thickness reduction, as any further lowering beyond this would start affecting efficiency (see Day 2: TaiyangNews High Efficiency Solar Technologies 2024 Conference).

Both CPIA and ITRPV project a continuous decrease in wafer thickness, although their forecasts differ in specific figures and timelines. According to CPIA, HJT technology has led wafer thickness reduction efforts, reaching 110 µm last year. This is expected to further decrease to 105 µm this year and to 100 µm by 2026, although the pace of reduction is anticipated to slow thereafter, reaching 90 µm by 2030. In comparison, ITRPV projects relatively higher wafer thicknesses. According to ITRPV, wafer thickness is expected to decline from 125 µm last year to below 120 µm this year, eventually reaching 100 µm by 2032.

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异质结电池 HJT 晶圆技术 太阳能
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